Stainless Steel Calcium Chloride Tank Lining, Suffolk

THE PROBLEM

As part of a significant multi million pound site expansion the client had ordered multiple stainless steel tanks. One of the tanks was to contain 42% Calcium Chloride solution which could operate at up to 90 Degrees Centigrade.

After extensive research the tank manufacturer could not find a grade of stainless steel that could withstand these operating temperatures.

Calcium chloride corrodes stainless steel in the following ways;

  • Pitting corrosion: Calcium chloride can cause pitting corrosion in stainless steel.
  • Chloride stress cracking: Common stainless steels can experience chloride stress cracking when exposed to liquid calcium chloride, even at temperatures as low as 100°F (38°C).
  • Reactivity: Calcium chloride is considered corrosive and reactive to many metals, including stainless steel.

THE SOLUTION

Given the elevated operating temperatures and chemical concentration we proposed the application of a glass flake reinforced vinyl ester lining in the form of Chemco International RB300.

Initially upon gaining access to the tank the internals were degreased using an emulsifying degreaser which was agitated using brooms and removed by high pressure water jetting.

To confirm the absence of soluble salts which left in place would lead to osmotic blistering in the tank lining, soluble salt tests were undertaken.

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The tank internals were checked for oil and grease contamination using a UV blacklight, which if present would disrupt the bond of the new tank lining to the substrate.

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Once we were satisfied that the tank internals were free from contaminants the internals were prepared by method of abrasive blasting to raise a suitable surface profile for the tank lining to adhere to.

It is important to test for contaminants before commencing abrasive blasting as the preparation works can force them further into the surface profile if present.

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The surface profile was tested and recorded using surface profile needle gauges in order to ensure that sufficient surface roughness has been achieved.

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Following abrasive blasting the tank internals were vacuumed clean and the effectiveness of this confirmed by conducting dust tape assessments. The presence of significant quantities of dust on the surface to which a tank lining is to be applied to will disrupt the proper adhesion of the tank lining.

Prior to tank lining application commencing heating and dehumidification was introduced to ensure the correct climatic conditions for coating application.

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As part of our standard quality assurance the climatic conditions were tested and monitored throughout the tank lining application process

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The tank internals were primed using Chemco RC300P Vinyl Ester primer applied by method of brush and roller to a nominal thickness of 50 microns.

Once cured all angles, edges and welds received a heavy stripe coat of Chemco RB364 applied by method of brush. Stripe coats are applied to areas where the tank lining will pull thin through surface tension. Applying an additional coat in these areas ensures that the desired tank lining thickness is achieved.

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Chemco RB364 was then applied in three coats to target thickness of 400 – 500 microns per coat to achieve a minimum tank lining thickness of 1200 microns.

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Wet film thicknesses readings were undertaken during the tank lining application and dry film thickness readings taken after each coat.

The tank lining was then tested for porosity using a DC Holiday spark tester in order to identify any pin holes that penetrated through the lining to the substrate.

This is an essential quality assurance check for tank linings as a single pin hole in an aggressive environment such as that found in this tank will allow the chemicals stored within the tank to reach the substrate and corrosion commence.

Any defects identified were marked prior to making good using the same tank lining material.

How does glass flake improve tank linings corrosion resistance ?

Glass flake is commonly used in coatings to improve corrosion resistance due to its unique physical and chemical properties. Here’s how it contributes to enhanced protection:

  1. Barrier Effect

Glass flakes, when incorporated into coatings, create a dense, layered structure that acts as a physical barrier. The flakes overlap within the coating, creating a tortuous path for corrosive agents such as water, oxygen, and chemicals to penetrate. This barrier effect significantly slows down the diffusion of these harmful elements to the substrate, thus delaying the onset of corrosion.

  1. Increased Coating Thickness

The addition of glass flake increases the overall thickness of the coating without compromising its flexibility or durability. This added thickness further prevents moisture and corrosive agents from reaching the underlying metal, offering extended protection in aggressive environments.

  1. Chemical Resistance

Glass flakes are chemically inert and non-reactive to many corrosive agents, including salts, acids, and alkalis. Their presence in coatings enhances the overall chemical resistance of the film, especially in environments exposed to aggressive chemicals, seawater, or industrial pollutants.

  1. Improved Mechanical Strength

Glass flakes improve the mechanical properties of coatings by reinforcing the matrix. This reinforcement increases the coating’s resistance to abrasion, impact, and mechanical wear, which can otherwise create openings for corrosive agents to reach the substrate.

  1. Thermal Stability

Glass flake-filled coatings exhibit improved thermal stability and can withstand higher temperatures without degradation. This is important in environments where temperature fluctuations could otherwise cause cracking or delamination of the coating, which would compromise its corrosion-resistant properties.

  1. Longer Lifespan

By enhancing the coating’s ability to resist permeation by moisture, chemicals, and air, glass flake extends the service life of the coating. This leads to longer intervals between maintenance, repairs, or recoating, which is particularly beneficial in offshore, marine, or industrial environments where corrosion is a constant threat.

  1. Prevention of Cathodic Disbondment

In systems where cathodic protection is used (such as pipelines or storage tanks), glass flake coatings resist cathodic disbondment—a phenomenon where coatings peel away due to electrochemical reactions. The glass flake’s barrier properties prevent this disbondment by limiting the flow of ions that could weaken the adhesion between the coating and the substrate.

Conclusion

By incorporating glass flake into coatings, the material benefits from enhanced corrosion protection, longer lifespan, and better resistance to environmental and mechanical stress. These improvements make glass flake-reinforced coatings ideal for use in harsh environments, such as marine, industrial, and offshore applications.